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荧光与磷光 fluorescence & phosphorescence

已有 3320 次阅读 2017-10-19 16:24 |系统分类:科研笔记|关键词:学者

(from Wikipedia)


Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore lower energy, than the absorbed radiation. The most striking example of fluorescence occurs when the absorbed radiation is in the ultraviolet region of the spectrum, and thus invisible to the human eye, while the emitted light is in the visible region, which gives the fluorescent substance a distinct color that can only be seen when exposed to UV light. Fluorescent materials cease to glow immediately when the radiation source stops, unlike phosphorescence, where it continues to emit light for some time after.


Phosphorescence is a type of photoluminescence related to fluorescence. Unlike fluorescence, phosphorescent material does not immediately re-emit the radiation it absorbs. The slower time scales of the re-emission are associated with "forbidden" energy state transitions in quantum mechanics. As these transitions occur very slowly in certain materials, absorbed radiation is re-emitted at a lower intensity for up to several hours after the original excitation.

Everyday examples of phosphorescent materials are the glow-in-the-dark toys, stickers, paint, and clock dials that glow for some time after being charged with a bright light such as in any normal reading or room light. Typically, the glow slowly fades out, sometimes within a few minutes or up to a few hours in a dark room.




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