||||
题目:Coordination-resolved electron spectrometrics
介绍: 471 参考文献; 65 图; 24 表; 49,000 字
杂志:Chemical Reviews (Online)
线上: http://pubs.acs.org/doi/abs/10.1021/cr500651m
内容:
1)问题: 原子尺度点缺陷,表皮,界面处化学键与电子的行为。
2)方法:专利(ZPS) + 键弛豫(BOLS)+非键电子极化(NEP) +紧束缚(TB)相结合。
3) 突破:STM/S、XPS、UPS、 AES、 APECS等能谱技术的局限
2)功能:原子尺度、局域、动态、定量的有关非理想配位原子间的键长、键能、能量密度、原子结合能。
3)分辨:三维面态、二维边态、一维端态、界面态、局域钉扎极化、Dirac-Fermi极化子、成键、非键、激子、晶场屏蔽与劈裂、等
4)欠配位:单原子厚度表层;点缺陷,台阶、晶界、纳米颗粒,单原子链、单原子薄带、外延原子、等。
5)混配位:杂质、界面、合金、吸附、氧化、非晶、四面体轨道杂化、等。
Electron Spectrometrics resolves atomistic, dynamic, local, and quantitative information of bond length, bond energy, charge quantum entrapment and polarization, energy densityand atomic cohesive energy pertaining to adatoms, point defects, monolayerskins, terrace edges, impurities, interfaces, atomic clusters, nanograins, andthe joint effect of under- and hetero-coordination. This strategy may lead to asubject area of coordination-resolved bond-electron-phonon-photon Spectrometrics
Archiver|手机版|科学网 ( 京ICP备07017567号-12 )
GMT+8, 2023-3-29 13:28
Powered by ScienceNet.cn
Copyright © 2007- 中国科学报社