jyx123321的个人博客分享 http://blog.sciencenet.cn/u/jyx123321 高分子材料/复合材料/物理凝胶 山东大学材料科学与工程学院教授

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聚电解质水凝胶体积变化的多相模型的研究论文在JCP上接受发表

已有 5106 次阅读 2010-9-1 21:00 |个人分类:未分类|系统分类:科研笔记|关键词:学者| 水凝胶, 聚电解质, 溶胀, 体积变化, 多相模型

        冯立刚同学主笔的研究论文A multiphasic model for the volume change of polyelectrolyte hydrogels被The Journal of Chemical Physics接受发表了!Doi: 10.1063/1.3484236。值得祝贺!

ABSTRACT:

A multiphasic model for the volume change of polyelectrolyte hydrogels that takes into account conservation of mass and momentum is derived. The gradient of chemical/electrochemical potentials of water and mobile ions is taken as the driving force for the volume change of the polyelectrolyte hydrogel, which is damped by the frictional forces between different phases and balanced by the elastic restoring force of the polymer network. Employing the model constructed here, the free swelling of a spherical polyelectrolyte hydrogel immersed in salt solution is simulated by the finite element method. The simulation shows that the polyelectrolyte hydrogel swells from the surface to the interior when the concentration of the external salt solution decreases. The swelling kinetics for ordinary hydrogels with high frictional coefficient between the polymer network and water is controlled by the collective diffusion of the polymer network, while for fast-response hydrogels it is controlled by the ionic diffusion in the hydrogel.



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