孙世刚院士团队 EER 最新综述 ︱ 低温燃料电池 电 催化剂的合理设计 与 合成 最新综述： 本文以阴极和阳极反应的合理设计为重点，综述了燃料电池质子交换膜（ PEMFC ）电催化剂的最 新研究成果 。这些设计基于模型表面刻度获得活性中心 , 包括用于阳极电氧化反应的高指数晶面铂和铂合金纳米晶 ， 以及用于阴极氧还原反应（ ORR ）的铂基合金 / 核 − 壳结构和碳基非贵金属催化剂。重点评述了用于阳极催化剂的高指数纳米晶、合金纳米颗粒及其载体效应，着重介绍了阴极催化剂方面具有新颖结构和不同组份的 ORR 电催化剂的最新进展，还综述了碳基非贵金属催化剂的活性中心结构、催化性能及其在燃料电池中的稳定性 。此外，展望了先进燃料电池电催化剂的发展前景和现状。 Rational Design and Synthesis of Low‑Temperature Fuel Cell Electrocatalysts Abstract: Recent progresses in proton exchange membrane fuel cell electrocatalysts are reviewed in this article in terms of cathodic and anodic reactions with a focus on rational design. These designs are based around gaining active sites using model surface studies and include high-index faceted Pt and Pt-alloy nanocrystals for anodic electrooxidation reactions as well as Pt-based alloy/core–shell structures and carbon-based non-precious metal catalysts for cathodic oxygen reduction reactions (ORR).High-index nanocrystals, alloy nanoparticles, and support effects are highlighted for anodic catalysts, and current developments in ORR electrocatalysts with novel structures and different compositions are emphasized for cathodic catalysts. Active site structures, catalytic performances, and stability in fuel cells are also reviewed for carbon-based non-precious metal catalysts.In addition, further developmental perspectives and the current status of advanced fuel cell electrocatalysts are provided. 文章信息 文章将发表于 EER 期刊 2018 年第 1 卷第 1 期，详情请阅读全文，可免费下载。 文章题目 ： Rational Design and Synthesis of Low‑Temperature Fuel CellElectrocatalysts 引用信息 ： Tian, N., Lu, BA., Yang, XD. et al. Electrochem. Energ. Rev. (2018). https://doi.org/10.1007/s41918-018-0004-1 关键词 ： 燃 料电池，铂，非贵金属催化剂，纳米晶，活性中心，电催化 全文链接 ： https://link.springer.com/article/10.1007/s41918-018-0004-1/fulltext.html 原文（扫描或长按二维码，识别后直达原文页面）： Biographies of Authors Na Tian (first author) received her Ph.D. degree from Xiamen University in 2007 and is now a professor at this University. Her research interests focus on metal nanocrystals with high-energy surfaces, electrocatalysts for oxygen reduction reaction, oxidation of small organic molecules,and CO 2 reduction. Bang - An Lu obtained his M.S. from Harbin Engineering University in 2012. He is currently pursuing a Ph.D. program in Physical Chemistry at Xiamen University. His research interests focus on exploring novel oxygen reduction reaction catalysts. Xiao-Dong Yang received his Ph.D. degree in material science and engineering from Xi’an Jiaotong University in 2014, and then spent 3 years as a post-doctoral fellow at Xiamen University. He became a Lecturer at Huaqiao University in 2017. His current research focuses on the development of polymer electrolyte fuel cells and electrocatalysts. Rui Huang obtained her Ph.D. degree from Xiamen University in 2013, and then did 3 years of postdoctoral research at the Collaborative Innovation Center of Chemistry for Energy Materials. She is actually an engineer at the Department of Chemistry. Her research interests include electrocatalysis, controlled synthesis of nanomaterials, and electrochemical in situ FTIR spectroscopy. Yan-Xia Jiang received her Ph.D. degree from Jilin University in 1999, and then joined the department of Chemistry at Xiamen University and was promoted to full professor in 2007. Her current research interests include electrochemical surface science, electrocatalysis and spectroelectrochemistry. Zhi-You Zhou received his Ph.D. degree in 2004 from Xiamen University and is a professor at the College of Chemistry and Chemical Engineering. His research interests include electrocatalysis, non-precious metal catalysts, fuel cells, and electrochemical in situ FTIR spectroscopy. Shi‑Gang Sun (corresponding author) obtained Doctorat d’Etat in 1986 from Université Pierre et Marie Curie (Paris VI), France, and is a professor of chemistry at Xiamen University. His research interests include electrocatalysis, electrochemical surface science, spectroelectrochemistry, and electrochemical energy conversion and storage. He has been elected Academician of Chinese Academy of Sciences, Fellow of Royal Society of Chemistry and Fellow of International Society of Electrochemistry. 杂志介绍 Electrochemical Energy Reviews (《电化学能源评论》，简称EER)，该期刊旨在及时反映国际电化学能源转换与存储领域的最新科研成果和动态，促进国内、国际的学术交流，设有专题综述和一般综述栏目。EER是国际上第一本专注电化学能源的综述性期刊。EER覆盖化学能源转换与存储所有学科，包括燃料电池，锂电池，金属-空气电池，超级电容器，制氢-储氢，CO 2 转换等。 EER为季刊，每年3月、6月、9月以及12月出版。 创刊号将在 2018 年3月正式出版。 欢迎关注和投稿 期刊执行严格的同行评议，提供英文润色、图片精修、封面图片设计等服务。出版周期 3个月左右，高水平论文可加快出版。欢迎关注和投稿 。 联系我们 E-mail eer@oa.shu.edu.cn Web http://www.springer.com/chemistry/electrochemistry/journal/41918 http://www.eer.shu.edu.cn Tel 86-21-66136010 长按 /扫描关注EER微信公众号
标签: 非贵金属催化剂
