相关文献下载： ICBA的历史.rar ICBA的历史.pdf 最近在与师弟师妹的讨论中发现他们对于 ICBA 这个非常优秀的材料的历史不了解，毕竟他们都是物理和电子学背景的，对有机电子学的合成部分，凡是涉及到分子式的就一概略过了。特写一个简单的文章，希望对师弟师妹们有所帮助 。 Chinese Version ICBA 于 1997 年第一次合成得到的； 2008 年第一次用于太阳能电池，效率为 5.1% ，可惜被申请了专利； 2010 年何有军师兄在很多富勒烯衍生物中筛选出 ICBA 这个分子，并且成功优化到 5.44%, 赵师兄进一步优化到了 6.5%, 之后他们组对 ICBA 及相关衍生物进行了一系列的优化和系统性研究。 ICBA 是一个非常优秀的材料，因为它的易制备，高溶解性，高 LUMO 值，高 Voc 值等，近几年对其及衍生进行了大量的研究，如三元体系，电荷转移，倒置电池等。 缺点是 1 ） ICBA 及相关早被申请了大量的专利 2 ） LUMO 太高，与很多聚合物的能级不匹配，只与 P3HT 有很好的效果。 窃以为，如果有 LUMO 值高于 PCBM 在 0.05~0.12eV ，且是少于 4 个的富勒烯 C60 衍生物的会非常有前途，不过我还有找到，同时也没有别人找到 :( PCBM 是 1995 年第一次被 Wuld 合成出来 1 ，俞刚第一次将其与 MEH-PPV 共混得到 2.9% 的效率 2 ， PCBM 的广泛研究中， Wuld 的文章一直是被提到的，同样对 ICBA 的研究中， Neilands 3 和 Laird 4,5 的铺垫性工作也是需要提到的，我们的每一份学术成果都是踏在前辈的脚印和尸体上。 English Version ICBA, Indene C60 Bi adduct. 茚与 C60 双加成物 History of ICBA (Indene C60 Biadduct) from synthesis, application, opimization. ICBA was a very excellent fullerene material, which waseasy to prepare, high solubility, high LUMO level and high Voc. It's was firstly synthesis in 1997, first application in OPV in 2009, first opimization with PCE=5.44% in2010.Much study have been done after ICBA's reexplorer in 2010 by Dr. He You-jun and Prof. Dr. Li Yong-fang, such as, e.g. ternary material, charge transfer, inverted cells. Below is its detailed history. 1) C60ICBA, Ref 3 First synthesis of ICBA in 1997 2) ICBA 太阳能电池 PCE=5.1%, 专利 Ref 4,5 ICBA's First Application in organic photovoltaic in 2008, patent. 3) ICBA 用于太阳能电池的优化， PCE=5.44%, Ref 6 Optimization of ICBA in OPV in 2010 4) ICBA 用于太阳能电池的进一步优化， PCE=6.5% ， Ref 7 Further Optimization of ICBA 5) ICBA 用于太阳能电池 , PCE=5.79%, Ref 8 ICBA's first application in OPV 6) 将 MoO3 取代 PEDOT:PSS ， ICBA 的器件优化 ,Ref 9 ICBA's application in OPV with MoO3 instead of PEDOT:PSS in 2012 7) ICBA 相关文章，自从 2010 年李永舫老师和何有军师兄发掘了 ICBA 这个非常优秀的材料易制备，高溶解性，高 LUMO 值和高 Voc 值后，业界对其做了大量的研究，做了很多相关研究，如三元体，电荷转移，倒置电池等。 ， Ref 10-16 Much study have been done after ICBA's reexplorer in 2010 by Dr. He You-jun and Prof. Dr. Li Yong-fang, such as ease to prepare, high solubility, high LUMO level and high Voc, e.g. ternary material, charge transfer, inverted cells. Topliuchao@gmail.com 2012-2-11 9:46:32 References: (1) J. C. Hummelen, B. W. Knight, F. Lepeq, F. Wudl, J. Yao, C. L. Wilkins, "PREPARATION AND CHARACTERIZATION OF FULLEROID AND METHANOFULLERENE DERIVATIVES", Journal of Organic Chemistry , 1995 , 60 , 532. (2) G. Yu, J. Gao, J. C. Hummelen, F. Wudl, A. J. Heeger, "Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions", Science , 1995 , 270 , 1789. (3) Austris Puplovskis, Janis Kacens, Ojars Neilands, "New route for fullerene functionalisation in cycloaddition reaction using indene", Tetrahedron Letters , 1997 , 38 , 285. (4) Darin W. Laird, Reza Stegamat, Henning Richter, Viktor Vejins, Larry Scott, Lada; Thomas A., "ORGANIC PHOTOVOLTAIC DEVICES COMPRISING FULLERENES AND DERIVATIVES THEREOF", 2008 ,WO/2008/018931. (5) Darin W. Laird, Henning Richter, Viktor Vejins, Lowrence Scott, Lada; Thomas A., Reza Stegamat, Daadi Malika, "Organic photovoltaic devices comprising fullerenes and derivatives thereof and improved methods of making fullerene derivatives", 2009 ,WO2009086210A2. (6) Y. J. He, H. Y. Chen, J. H. Hou, Y. F. Li, "Indene-C-60 Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells", Journal of the American Chemical Society , 2010 , 132 , 1377. (7) Guangjin Zhao, Youjun He, Yongfang Li, "6.5% Efficiency of Polymer Solar Cells Based on poly(3-hexylthiophene) and Indene-C60 Bisadduct by Device Optimization", Advanced Materials , 2010 , 9999 , NA. (8) Y. J. He, G. J. Zhao, B. Peng, Y. F. Li, "High-Yield Synthesis and Electrochemical and Photovoltaic Properties of Indene-C-70 Bisadduct", Advanced Functional Materials , 2010 , 20 , 3383. (9) Xi Fan, Chaohua Cui, Guojia Fang, Jinzhao Wang, Songzhan Li, Fei Cheng, Hao Long, Yongfang Li, "Efficient Polymer Solar Cells Based on Poly(3-hexylthiophene):Indene-C70 Bisadduct with a MoO3 Buffer Layer", Advanced Functional Materials , 2012 , 22 , 585. 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(14) Youjun He, Hsiang-Yu Chen, Guangjin Zhao, Jianhui Hou, Yongfang Li, "Synthesis and photovoltaic properties of biindene-C70 monoadduct as acceptor in polymer solar cells", Solar Energy Materials and Solar Cells , 2011 , 95 , 1762. (15) Yen-Ju Cheng, Chao-Hsiang Hsieh, Youjun He, Chain-Shu Hsu, Yongfang Li, "Combination of Indene-C60 Bis-Adduct and Cross-Linked Fullerene Interlayer Leading to Highly Efficient Inverted Polymer Solar Cells", Journal of the American Chemical Society , 2010 , 132 , 17381. (16) Petr P. Khlyabich, Beate Burkhart, Barry C. Thompson, "Efficient Ternary Blend Bulk Heterojunction Solar Cells with Tunable Open-Circuit Voltage", Journal of the American Chemical Society , 2011 , 133 , 14534.
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