近日微信上看到相关介绍。大致内容与这个网页写的类似 http://jandan.net/2016/04/24/water-new-state.html 科学网也有介绍: http://news.sciencenet.cn/htmlnews/2016/4/344295.shtm 原文在这里 http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.116.167802 皇家化学会介绍 http://www.rsc.org/chemistryworld/2016/04/new-state-water-delocalised-protons “H owever, other researchers will probably want to scrutinise these calculations carefully before accepting the claims. And whether this genuinely qualifies as a ‘new phase of water’ seems likely to excite some debate. The molecule is, after all, unchanged, other than switching between several energetically equivalent states . ‘This looks to me like just a realisation of quantum mechanics and not so different from what water will do on this same potential energy surface at higher temperatures when it is classically rotating,’ says Angelos Michaelides of University College London ” 感觉原文作者没有普通化学知识,把量子力学得出的多个状态的平均当成体系在某个时间点存在的状态。一个简单的问题是体系的初始状态是什么,几个氢原子,几个氧原子?